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Garnet gemstone

The garnet group of minerals show crystals with a habit of rhombic dodecahedrons and trapezohedrons. They are nesosilicates with the same general formula, A3B2(SiO4)3. The chemical elements in garnet include calcium, magnesium, aluminium, iron2+, iron3+, chromium, manganese, and titanium. Garnets show no cleavage and a dodecahedral parting. Fracture is conchoidal to uneven; some varieties are very tough and are valuable for abrasive purposes. Hardness is 6.5 - 7.5, specific gravity is 3.1 - 4.3, luster is vitreous to resinous, and they can be transparent to opaque.
The name "garnet" comes from the Latin granatus, a grain possibly in reference to malum granatum (pomegranate) a plant with red seeds similar in shape, size and color to some garnet crystals.

Garnet a group of minerals

There is a misconception that garnets are only a red gem but in fact they come in a variety of colors including purple, red, orange, yellow, green, brown, black, or colorless. The lack of a blue garnet was remedied in 1990's following the discovery of color-change blue to red/pink material in Bekily, Madagascar but these stones are very rare. Color-change garnets are by far the rarest garnets except uvarovite, which does not come in cuttable sizes. In daylight, their color can be shades of green, beige, brown, gray and rarely blue, to a reddish or purplish/pink color in incandescent light. By composition, these garnets are a mix of spessartine and pyrope, as are Malaya garnets. The color change of these new garnets is often more intense and more dramatic than the color change of top quality Alexandrite which is frequently disappointing, but still sells for many thousands of dollars (US) per carat. It is expected that blue color-change garnets will match Alexandrite prices or even exceed them as the color change is often better and these garnets are much rarer. The blue color-change type is mainly caused by relatively high amounts of vanadium (about 1 wt.% V2O3).

Six common varieties of garnet are recognized based on their chemical composition. They are pyrope, almandine or carbuncle, spessartite, grossularite (varieties of which are hessonite or cinnamon-stone and tsavorite), uvarovite and andradite. The garnets make up two solid solution series; 1. pyrope-almandine-spessarite and 2. uvarovite-grossularite-andradite.
Garnet is the birthstone for January, and has been used since the Bronze Age.
Almandite, sometimes called almandine, is the modern gem known as carbuncle (though originally almost any red gemstone was known by this name). The term "carbuncle" is derived from the Latin meaning "little spark." The name Almandite is a corruption of Alabanda, a region in Asia Minor where these stones were cut in ancient times. Chemically, almandite is an iron-aluminium garnet with the formula Fe3Al2(SiO4)3; the deep red transparent stones are often called precious garnet and are used as gemstones (being the most common of the gem garnets). Almandite occurs in metamorphic rocks like mica schists, associated with minerals such as staurolite, kyanite, andalusite, and others. Almandite has nicknames of Oriental garnet, almandine ruby, and carbuncle.

Pyrope, from the Latin pyropos, means similar to fire. It is ruby-red in color and chemically a magnesium aluminium silicate with the formula Mg3Al2(SiO4)3, though the magnesium can be replaced in part by calcium and ferrous iron. The color of pyrope varies from deep red to almost black. Transparent pyropes are used as gemstones.
A variety of pyrope from Macon County, North Carolina is a violet-red shade and has been called rhodolite, from the Greek meaning "a rose." In chemical composition it may be considered as essentially an isomorphous mixture of pyrope and almandite, in the proportion of two parts pyrope to one part almandite. Pyrope has nicknames of Cape ruby, Arizona ruby, California ruby, Rocky Mountain ruby, and Bohemian garnet from the Czech Republic. Another intriguing find is the blue color-change garnets from Madagascar, a pyrope spessatine mix. The color of these blue garnets is not like sapphire blue in subdued daylight but more reminiscent of the grayish blues and greenish blues sometimes seen in spinel However in white LED light the color is equal to the best corn flower blue sapphire or D block tanzanite this is due to the blue garnets ability to absorb the yellow component of the emitted light.
Pyrope is an indicator mineral for high pressure rocks. The garnets from mantle derived rocks, peridotites and eclogites, commonly contain a pyrope variety
Spessartite or spessartine is manganese aluminium garnet, Mn3Al2(SiO4)3. Its name is derived from Spessart in Bavaria. It occurs most often in granite pegmatite and allied rock types and in certain low grade metamorphic phyllites. Spessartite of a beautiful orange-yellow is found in Madagascar (see Mandarin garnet). Violet-red spessartites are found in rhyolites in Colorado and Maine.

Ugrandite group - calcium in A site
Andradite: Ca3Fe2(SiO4)3
Grossular: Ca3Al2(SiO4)3
Uvarovite: Ca3Cr2(SiO4)3
Andradite is a calcium-iron garnet, Ca3Fe2(SiO4)3, is of variable composition and may be red, yellow, brown, green or black. The recognized subvarieties are topazolite (yellow or green), demantoid (green) and melantite (black). Andradite is found both in deep-seated igneous rocks like syenite as well as serpentines, schists, and crystalline limestone. Demantoid has been called the "emerald of the Urals" from its occurrence there, and is one of the most prized of garnet varieties. Topazolite is a golden yellow variety and melanite is a black variety.

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