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The garnet group of minerals show crystals with a habit of rhombic
dodecahedrons and trapezohedrons. They are nesosilicates with the
same general formula, A3B2(SiO4)3. The chemical elements in garnet
include calcium, magnesium, aluminium, iron2+, iron3+, chromium,
manganese, and titanium. Garnets show no cleavage and a dodecahedral
parting. Fracture is conchoidal to uneven; some varieties are very
tough and are valuable for abrasive purposes. Hardness is 6.5 - 7.5,
specific gravity is 3.1 - 4.3, luster is vitreous to resinous, and
they can be transparent to opaque.
The name "garnet" comes from the Latin granatus, a grain possibly in
reference to malum granatum (pomegranate) a plant with red seeds
similar in shape, size and color to some garnet crystals. |
Garnet a group of minerals
There is a misconception that garnets are only a red gem but in
fact they come in a variety of colors including purple, red, orange,
yellow, green, brown, black, or colorless. The lack of a blue garnet
was remedied in 1990's following the discovery of color-change blue
to red/pink material in Bekily, Madagascar but these stones are very
rare. Color-change garnets are by far the rarest garnets except
uvarovite, which does not come in cuttable sizes. In daylight, their
color can be shades of green, beige, brown, gray and rarely blue, to
a reddish or purplish/pink color in incandescent light. By
composition, these garnets are a mix of spessartine and pyrope, as
are Malaya garnets. The color change of these new garnets is often
more intense and more dramatic than the color change of top quality
Alexandrite which is frequently disappointing, but still sells for
many thousands of dollars (US) per carat. It is expected that blue
color-change garnets will match Alexandrite prices or even exceed
them as the color change is often better and these garnets are much
rarer. The blue color-change type is mainly caused by relatively
high amounts of vanadium (about 1 wt.% V2O3).
Six common varieties of garnet are recognized based on their
chemical composition. They are pyrope, almandine or carbuncle,
spessartite, grossularite (varieties of which are hessonite or
cinnamon-stone and tsavorite), uvarovite and andradite. The garnets
make up two solid solution series; 1. pyrope-almandine-spessarite
and 2. uvarovite-grossularite-andradite.
Garnet is the birthstone for January, and has been used since the
Bronze Age.
Almandite, sometimes called almandine, is the modern gem known as
carbuncle (though originally almost any red gemstone was known by
this name). The term "carbuncle" is derived from the Latin meaning
"little spark." The name Almandite is a corruption of Alabanda, a
region in Asia Minor where these stones were cut in ancient times.
Chemically, almandite is an iron-aluminium garnet with the formula
Fe3Al2(SiO4)3; the deep red transparent stones are often called
precious garnet and are used as gemstones (being the most common of
the gem garnets). Almandite occurs in metamorphic rocks like mica
schists, associated with minerals such as staurolite, kyanite,
andalusite, and others. Almandite has nicknames of Oriental garnet,
almandine ruby, and carbuncle.
Pyrope, from the Latin pyropos, means similar to fire. It is
ruby-red in color and chemically a magnesium aluminium silicate with
the formula Mg3Al2(SiO4)3, though the magnesium can be replaced in
part by calcium and ferrous iron. The color of pyrope varies from
deep red to almost black. Transparent pyropes are used as gemstones.
A variety of pyrope from Macon County, North Carolina is a
violet-red shade and has been called rhodolite, from the Greek
meaning "a rose." In chemical composition it may be considered as
essentially an isomorphous mixture of pyrope and almandite, in the
proportion of two parts pyrope to one part almandite. Pyrope has
nicknames of Cape ruby, Arizona ruby, California ruby, Rocky
Mountain ruby, and Bohemian garnet from the Czech Republic. Another
intriguing find is the blue color-change garnets from Madagascar, a
pyrope spessatine mix. The color of these blue garnets is not like
sapphire blue in subdued daylight but more reminiscent of the
grayish blues and greenish blues sometimes seen in spinel However in
white LED light the color is equal to the best corn flower blue
sapphire or D block tanzanite this is due to the blue garnets
ability to absorb the yellow component of the emitted light.
Pyrope is an indicator mineral for high pressure rocks. The garnets
from mantle derived rocks, peridotites and eclogites, commonly
contain a pyrope variety
Spessartite or spessartine is manganese aluminium garnet,
Mn3Al2(SiO4)3. Its name is derived from Spessart in Bavaria. It
occurs most often in granite pegmatite and allied rock types and in
certain low grade metamorphic phyllites. Spessartite of a beautiful
orange-yellow is found in Madagascar (see Mandarin garnet).
Violet-red spessartites are found in rhyolites in Colorado and
Maine.
Ugrandite group - calcium in A site
Andradite: Ca3Fe2(SiO4)3
Grossular: Ca3Al2(SiO4)3
Uvarovite: Ca3Cr2(SiO4)3
Andradite is a calcium-iron garnet, Ca3Fe2(SiO4)3, is of variable
composition and may be red, yellow, brown, green or black. The
recognized subvarieties are topazolite (yellow or green), demantoid
(green) and melantite (black). Andradite is found both in
deep-seated igneous rocks like syenite as well as serpentines,
schists, and crystalline limestone. Demantoid has been called the
"emerald of the Urals" from its occurrence there, and is one of the
most prized of garnet varieties. Topazolite is a golden yellow
variety and melanite is a black variety. |